Electrolyte tuning of electrode potentials: the one electron vs. two electron reduction of anthraquinone-2-sulfonate in aqueous media.
The electrode potentials of quinone redox centres in aqueous solutions can be tuned by varying the electrolyte cation identity. The phenomenon is due to the ion pairing effect of the tetra-n-butylammonium cation with the semiquinone intermediate species.
主要な著者: | Li, Q, Batchelor-McAuley, C, Lawrence, N, Hartshorne, R, Compton, R |
---|---|
フォーマット: | Journal article |
言語: | English |
出版事項: |
2011
|
類似資料
-
The anthraquinone mediated one-electron reduction of oxygen in acetonitrile
著者:: Nissim, R, 等
出版事項: (2012) -
Voltammetric characterization of DNA intercalators across the full pH range: anthraquinone-2,6-disulfonate and anthraquinone-2-sulfonate.
著者:: Batchelor-McAuley, C, 等
出版事項: (2010) -
Semiquinone intermediates in the two-electron reduction of quinones in aqueous media and their exceptionally high reactivity towards oxygen reduction.
著者:: Li, Q, 等
出版事項: (2011) -
Anomalous solubility of oxygen in acetonitrile/water mixture containing tetra-n-butylammonium perchlorate supporting electrolyte; the solubility and diffusion coefficient of oxygen in anhydrous acetonitrile and aqueous mixtures
著者:: Li, Q, 等
出版事項: (2013) -
Voltammetry of multi-electron electrode processes of organic species
著者:: Batchelor-McAuley, C, 等
出版事項: (2012)