REDOX-RESPONSIVE MOLYBDENUM MONONITROSYL COMPLEXES INCORPORATING CYCLIC POLYETHER CATION BINDING-SITES AND X-RAY CRYSTAL-STRUCTURE OF [MO(NO)(HB(3,5-ME2C3N2H)3)(OCH2(CH2OCH2)3CH2O)]
The complexes [Mo(NO){HB(Me2pz)3}{OCH2(CH2OCH 2)nCH2O}] (n = 2-5; HB(Me2pz)3- = hydrotris(3,5-dimethylpyrazolyl)borate) have been synthesized and characterized by spectroscopic methods. All contain the redox-active {Mo(NO)}3+ moiety incorporated in an unusually large chelate ring which forms a cycli...
| Main Authors: | , , , , , , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
1992
|