REDOX-RESPONSIVE MOLYBDENUM MONONITROSYL COMPLEXES INCORPORATING CYCLIC POLYETHER CATION BINDING-SITES AND X-RAY CRYSTAL-STRUCTURE OF [MO(NO)(HB(3,5-ME2C3N2H)3)(OCH2(CH2OCH2)3CH2O)]

REDOX-RESPONSIVE MOLYBDENUM MONONITROSYL COMPLEXES INCORPORATING CYCLIC POLYETHER CATION BINDING-SITES AND X-RAY CRYSTAL-STRUCTURE OF [MO(NO)(HB(3,5-ME2C3N2H)3)(OCH2(CH2OCH2)3CH2O)]

The complexes [Mo(NO){HB(Me2pz)3}{OCH2(CH2OCH 2)nCH2O}] (n = 2-5; HB(Me2pz)3- = hydrotris(3,5-dimethylpyrazolyl)borate) have been synthesized and characterized by spectroscopic methods. All contain the redox-active {Mo(NO)}3+ moiety incorporated in an unusually large chelate ring which forms a cycli...

Bibliografske podrobnosti
Main Authors:	Alobaidi, N, Salam, S, Beer, P, Bush, C, Hamor, T, Mcquillan, F, Jones, C, Mccleverty, J
Format:	Journal article
Jezik:	English
Izdano:	1992

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