Dynamics of the reaction O(P-3)+H2S -> OH+SH. 1. Rotational, Lambda doublet, and fine structure distributions in the OH(upsilon ''=1) product
Rotational, spin-orbit, and A doublet populations have been measured in the OH(ν″ = 1) product of the O(3P) + H2S reaction. Ground-state O atoms with kinetic energies above the barrier to reaction were formed by photolysis of NO2 at 355 nm. Rotational populations were found to be hotter than statist...
| Автори: | , , |
|---|---|
| Формат: | Journal article |
| Мова: | English |
| Опубліковано: |
1999
|