Dynamics of the reaction O(P-3)+H2S -> OH+SH. 1. Rotational, Lambda doublet, and fine structure distributions in the OH(upsilon ''=1) product
Rotational, spin-orbit, and A doublet populations have been measured in the OH(ν″ = 1) product of the O(3P) + H2S reaction. Ground-state O atoms with kinetic energies above the barrier to reaction were formed by photolysis of NO2 at 355 nm. Rotational populations were found to be hotter than statist...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1999
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