Room temperature acceptorless alkane dehydrogenation from molecular σ-alkane complexes

The non-oxidative catalytic dehydrogenation of light alkanes via C–H activation is a highly endothermic process that generally requires high temperatures and/or a sacrificial hydrogen acceptor to overcome unfavorable thermodynamics. This is complicated by alkanes being such poor ligands, meaning tha...

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Váldodahkkit: McKay, AI, Bukvic, A, Tegner, BE, Burnage, A, Martinez-Martinez, A, Rees, NH, Macgregor, SA, Weller, A
Materiálatiipa: Journal article
Almmustuhtton: American Chemical Society 2019