Two total syntheses of trigoxyphins K and L
Two total syntheses are presented for trigoxyphins K and L, tricyclic terpenoids from Trigonostemon xyphophylloides. The first proceeds via electrophlic cyclization in A/C-ring substrates to close the B-ring at C4–C5 then 1 O2-mediated hydroxybutenolide formation to trigoxyphin L, with Luche reducti...
| Main Authors: | , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
American Chemical Society
2023
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