Development of an infrared spectroscopic approach for studying metalloenzyme active site chemistry under direct electrochemical control.
Direct electrochemical methods have been productive in revealing mechanistic details of catalysis by a range of metalloenzymes including hydrogenases and carbon and nitrogen cycling enzymes. In this approach, termed protein film electrochemistry, the protein is attached or adsorbed on the electrode...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2011
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