A short synthesis of aphanamol I in both racemic and enantiopure forms
A short synthesis of the biologically active sesquiterpene natural product (+)-aphanamol I in both racemic and enantiopure forms is reported. Key steps include: a catalytic enantioselective conjugate addition, an oxidative radical cyclisation, and a ringexpanding Claisen rearrangement.
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| Aineistotyyppi: | Journal article |
| Julkaistu: |
Wiley
2016
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| Yhteenveto: | A short synthesis of the biologically active sesquiterpene natural product (+)-aphanamol I in both racemic and enantiopure forms is reported. Key steps include: a catalytic enantioselective conjugate addition, an oxidative radical cyclisation, and a ringexpanding Claisen rearrangement. |
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