A short synthesis of aphanamol I in both racemic and enantiopure forms
A short synthesis of the biologically active sesquiterpene natural product (+)-aphanamol I in both racemic and enantiopure forms is reported. Key steps include: a catalytic enantioselective conjugate addition, an oxidative radical cyclisation, and a ringexpanding Claisen rearrangement.
Những tác giả chính: | , |
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Định dạng: | Journal article |
Được phát hành: |
Wiley
2016
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_version_ | 1826276125941170176 |
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author | Burton, J Ferrara, S |
author_facet | Burton, J Ferrara, S |
author_sort | Burton, J |
collection | OXFORD |
description | A short synthesis of the biologically active sesquiterpene natural product (+)-aphanamol I in both racemic and enantiopure forms is reported. Key steps include: a catalytic enantioselective conjugate addition, an oxidative radical cyclisation, and a ringexpanding Claisen rearrangement. |
first_indexed | 2024-03-06T23:09:17Z |
format | Journal article |
id | oxford-uuid:64e7fa3b-18f7-453c-b44e-54a76b3f1439 |
institution | University of Oxford |
last_indexed | 2024-03-06T23:09:17Z |
publishDate | 2016 |
publisher | Wiley |
record_format | dspace |
spelling | oxford-uuid:64e7fa3b-18f7-453c-b44e-54a76b3f14392022-03-26T18:22:02ZA short synthesis of aphanamol I in both racemic and enantiopure formsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:64e7fa3b-18f7-453c-b44e-54a76b3f1439Symplectic Elements at OxfordWiley2016Burton, JFerrara, SA short synthesis of the biologically active sesquiterpene natural product (+)-aphanamol I in both racemic and enantiopure forms is reported. Key steps include: a catalytic enantioselective conjugate addition, an oxidative radical cyclisation, and a ringexpanding Claisen rearrangement. |
spellingShingle | Burton, J Ferrara, S A short synthesis of aphanamol I in both racemic and enantiopure forms |
title | A short synthesis of aphanamol I in both racemic and enantiopure forms |
title_full | A short synthesis of aphanamol I in both racemic and enantiopure forms |
title_fullStr | A short synthesis of aphanamol I in both racemic and enantiopure forms |
title_full_unstemmed | A short synthesis of aphanamol I in both racemic and enantiopure forms |
title_short | A short synthesis of aphanamol I in both racemic and enantiopure forms |
title_sort | short synthesis of aphanamol i in both racemic and enantiopure forms |
work_keys_str_mv | AT burtonj ashortsynthesisofaphanamoliinbothracemicandenantiopureforms AT ferraras ashortsynthesisofaphanamoliinbothracemicandenantiopureforms AT burtonj shortsynthesisofaphanamoliinbothracemicandenantiopureforms AT ferraras shortsynthesisofaphanamoliinbothracemicandenantiopureforms |