Synthesis and structure of low-dimensional gallium fluorodiphosphates seen during the crystallization of the three-dimensional microporous gallium fluorophosphate ULM-3

Two one-dimensional gallium fluorodiphosphates Ga(P2O7)F·H3 N(CH2)3NH3·3H2O, 1, and Ga(P2O7) F·H3N(CH2) 3NH3·H2O, 2, have been synthesized under mild conditions (<100°C) from aqueous mixtures of Ga(NO3)3·6H2O, P2O5, 1,3-diaminopropane, and HF. Their structures consist of anionic chains of for...

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Bibliographic Details
Main Authors: Millange, F, Walton, R, Guillou, N, Loiseau, T, O'Hare, D, Ferey, G
Format: Journal article
Language:English
Published: 2002