Asymmetric synthesis of the tetraponerine alkaloids
The asymmetric syntheses of all eight tetraponerine alkaloids (T1–T8) were achieved using the diastereoselective conjugate additions of lithium amide reagents in the key stereodefining steps. Conjugate addition of either lithium (R)-N-allyl-N-(α-methylbenzyl)amide or lithium (R)-N-(but-3-en-1-yl)-N-...
Main Authors: | , , , , |
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Format: | Journal article |
Published: |
American Chemical Society
2017
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