Synthesis of the infinite layer Ni(I) phase NdNiO2+x by low temperature reduction of NdNiO3 with sodium hydride
The infinite layer Ni(I) containing phase NdNiO2+x (x = 0.03) has been synthesised by low temperature reaction between NdNiO3 and NaH: reduction with H2 or metal gettering reagents does not afford this phase. The reaction path from the Ni(III) perovskite differs from the case of LaNiO2. Structural a...
| Main Authors: | , |
|---|---|
| Format: | Conference item |
| Published: |
2003
|