Gold(I)-catalyzed intermolecular hydroalkoxylation of allenes: a DFT study.

Gold(I)-catalyzed intermolecular hydroalkoxylation of allenes: a DFT study.

The mechanistic and regiochemical aspects in the Au(I)-catalyzed intermolecular hydroalkoxylation of allenes have been studied computationally. The most favorable pathway is nucleophilic attack of an Au(I)-coordinated allene, which occurs irreversibly. An Au(I)-catalyzed mechanism is proposed that a...

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Bibliografische gegevens
Hoofdauteurs:	Paton, R, Maseras, F
Formaat:	Journal article
Taal:	English
Gepubliceerd in:	2009

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