Enantio- and diastereoselective palladium catalysed arylative and vinylative allene carbocyclisation cascades.

Enantio- and diastereoselective palladium catalysed arylative and vinylative allene carbocyclisation cascades.

The enantioselective synthesis of heavily decorated spirolactams has been accomplished via an arylative or vinylative allene carbocyclisation cascade. Mediated by silver phosphate, a range of allene-linked pro-nucleophiles and aryl or vinyl iodides were reacted in the presence of catalytic Pd(OAc)2...

Полное описание

Библиографические подробности
Главные авторы:	Li, M, Hawkins, A, Barber, D, Bultinck, P, Herrebout, W, Dixon, D
Формат:	Journal article
Язык:	English
Опубликовано:	2013

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