Two epimerisations in the formation of oxetanes from L-rhamnose: towards oxetane-containing peptidomimetics

The methyl group in (R)-3,5-O-benzylidene-L-rhamnono-1,4-lactone 2, prepared from L-rhamnose 1 in 41% yield without need for chromatography, is axial and provides a good example of Mills' rule that the 'O-inside' conformations are, in general, more stable than alternative 'H-insi...

وصف كامل

التفاصيل البيبلوغرافية
المؤلفون الرئيسيون: Johnson, S, Angus, D, Taillefumier, C, Jones, J, Watkin, D, Floyd, E, Buchanan, J, Fleet, G
التنسيق: Journal article
اللغة:English
منشور في: 2000