Anomalous solubility of oxygen in acetonitrile/water mixture containing tetra-n-butylammonium perchlorate supporting electrolyte; The solubility and diffusion coefficient of oxygen in anhydrous acetonitrile and aqueous mixtures

We report the oxygen electro-reduction in air-saturated acetonitrile (MeCN) solution supported by 0.1 M tetra-n-butylammonium perchlorate salt under two experimental conditions: (1) anhydrous MeCN at elevated temperatures from 298.5 to 313.0 K on platinum electrodes; (2) water-mixed MeCN solution (m...

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Bibliographic Details
Main Authors: Li, Q, Batchelor-Mcauley, C, Lawrence, N, Hartshorne, R, Compton, R
Format: Journal article
Language:English
Published: 2013