New Sandwich and Half-Sandwich Titanium Hydrazido Compounds

New mono- and bis-cyclopentadienyl terminal titanium hydrazido(2-) compounds were prepared by tert-butyl imide/N,N-disubstituted hydrazine exchange reactions. Reaction of Cp*Ti(NtBu)Cl(py) (1) with Ph 2NNH2 gave the terminal hydrazide Cp*Ti(NNPh 2)Cl(py) (4), whereas the corresponding reaction of Cp...

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Bibliographic Details
Main Authors: Selby, J, Feliz, M, Schwarz, A, Clot, E, Mountford, P
Format: Journal article
Language:English
Published: 2011