STRUCTURE AND DYNAMICS OF INTERMEDIATES IN ASYMMETRIC HYDROGENATION BY RHODIUM COMPLEXES OF (2-METHOXYPHENYL)-P-PHENYL-P-(2'-DIPHENYLPHOSPHINO)ETHYLPHOSPHINE
The four rhodium enamide complexes formed from the title ligand and methyl Z-acetamidocinnamate undergo rapid pair-specific intramolecular exchange and give rise to a single alkylhydride under hydrogen below -40°C.
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1995
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