Magnesium, calcium and zinc [N2N'] heteroscorpionate complexes

A new family of sterically demanding N2N′ heteroscorpionate pro-ligands (HC(tBu2pz)2SiMe2N(H)R (R = iPr, tBu, Ph, Xyl)) has been prepared via a straightforward modular synthetic route. An extensive study into the synthesis and characterisation of lithium, magnesium, calcium and zinc complexes suppor...

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Bibliographic Details
Main Authors: Luna Barros, M, Cushion, M, Schwarz, A, Turner, Z, Mountford, P
Format: Journal article
Published: Royal Society of Chemistry 2019