Radical cascades using enantioenriched 7-azabenzonorbornenes and their applications in synthesis.
Tandem deoxygenation-neophyl-type radical rearrangement-electrophile trapping using xanthates from 7-azabenzonorbornadienes gives 3-exo-substituted 2-aza-5,6-benzonorbornenes, which in some cases undergo isomerisation to (aminomethyl)indenes. The starting xanthates are accessible in good yields and...
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2008
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