Potentiometric MRI of a super-concentrated lithium electrolyte: testing the irreversible thermodynamics approach

Super-concentrated electrolytes, being highly thermodynamically nonideal, provide a stringent proving ground for continuum transport theories. Here we test an ostensibly complete model of LiPF6 in ethyl-methyl carbonate (EMC) based on the Onsager–Stefan– Maxwell theory from irreversible thermodynami...

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Detalhes bibliográficos
Principais autores: Wang, A, Gunnarsdottir, A, Fawdon, J, Pasta, M, Grey, C, Monroe, C
Formato: Journal article
Idioma:English
Publicado em: American Chemical Society 2021