Total synthesis of polycephalin C and determination of the absolute configurations at the 3",4" ring junction.

Total synthesis of polycephalin C and determination of the absolute configurations at the 3",4" ring junction.

Only through total synthesis could the absolute configuration of the 3′′R,4′′R ring junction of the polyenoltetramic acid polycephalin C (1) be unambiguously established. Key features of the synthesis include a double Swern oxidation, double Stille coupling, and a double Takai olefination.

Библиографические подробности
Главные авторы:	Longbottom, D, Morrison, A, Dixon, D, Ley, S
Формат:	Journal article
Язык:	English
Опубликовано:	2002

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