The synthesis, characterization and dehydrogenation of sigma-complexes of BN-cyclohexanes

The coordination chemistry of the 1,2-BN-cyclohexanes 2,2-R2-1,2-B,N-C4H10 (R2=HH, MeH, Me2) with Ir and Rh metal fragments has been studied. This led to the solution (NMR spectroscopy) and solid-state (X-ray diffraction) characterization of [Ir(PCy3)2(H)2(η2η2-H2BNR2C4H8)][BArF4] (NR2=NH2, NMeH) an...

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Bibliographic Details
Main Authors: Kumar, A, Ishibashi, JSA, Hooper, TN, Mikulas, TC, Dixon, DA, Liu, S-Y, Weller, AS
Format: Journal article
Language:English
Published: Wiley 2015