Reactions of neutral and cationic diamide-supported imido complexes with CO2 and other heterocumulenes: Issues of site selectivity

Experimental and DFT computational studies of the reactions of the cationic diamide-pyridine-supported methyl tungsten complex [W(NPh)(N3N py)Me]+ (2+) with the heterocumulenes CO 2, CS2, RNCO, and RNCS (R = tert-butyl or aryl) are described, together with comparative studies of the group 5 compound...

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Bibliographic Details
Main Authors: Ward, B, Orde, G, Clot, E, Cowley, A, Gade, L, Mountford, P
Format: Journal article
Language:English
Published: 2005