Dioxygen activation by mixed-valent dirhodium complexes of redox non-innocent azoaromatic ligands.
The isolation, structural chracterisation and electronic structure of a formally mixed-valent Rh(-I)-Rh(III) complex is described, along with its reaction with dioxygen leading to double arene hydroxylation of the coordinated ligands.
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2010
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