BIFUNCTIONAL CHIRAL AUXILIARIES .7. ALDOL REACTIONS OF ENOLATES DERIVED FROM 1,3-DIACYLIMIDAZOLIDINE-2-THIONES AND 1,3-DIACYLIMIDAZOLIDIN-2-ONES
Dibutylboron enolates of 1,3-diacylimidazolidine-2-thiones and 1,3-diacylimidazolidin-2-ones undergo highly syn-stereoselective aldol reactions with aldehydes to allow elaboration of both acyl sidechains. The reaction is proposed to occur via sequential enolisation rather than via a bisenolate and t...
| Váldodahkkit: | , , , |
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| Materiálatiipa: | Journal article |
| Almmustuhtton: |
1994
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