Porphyrin-polyyne [3] and [5]rotaxanes
Porphyrin–polyyne [3]- and [5]rotaxanes have been synthesized by condensing aldehyde–rotaxanes with pyrrole or dipyrromethane. The crystal structure of a [3]rotaxane shows that the macrocycles adopt compact conformations, holding the hexaynes near the porphyrin core, and that the phenanthroline unit...
| Main Authors: | , , , |
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| Format: | Journal article |
| Published: |
American Chemical Society
2017
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