Experimental Comparison of the Marcus-Hush and Butler-Volmer Descriptions of Electrode Kinetics. The One-Electron Oxidation of 9,10-Diphenylanthracene and One-Electron Reduction of 2-Nitropropane Studied at High-Speed Channel Microband Electrodes

We present an experimental comparative evaluation of the Marcus-Hush (MH) and Butler-Volmer (BV) kinetic formalisms. Numerical simulations using both kinetic models are used to fit experimental voltammetry of the one-electron oxidation of 9,10-diphenylanthracene (DPA) and the one-electron reduction...

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Bibliographic Details
Main Authors: Suwatchara, D, Henstridge, M, Rees, N, Compton, R
Format: Journal article
Language:English
Published: 2011