Solid-State Organometallic Chemistry (SMOM): synthesis, alkane dehydrogenation and surface modification of crystalline σ-alkane complexes

Solid-State Organometallic Chemistry (SMOM): synthesis, alkane dehydrogenation and surface modification of crystalline σ-alkane complexes

This thesis reports the synthesis of single-crystalline σ-alkane complexes of rhodium. These are synthesised by the hydrogenation of precursor alkene or diene complexes in solid/gas single-crystal to single-crystal (SC-SC) transformations, using the Solid-State Molecular OrganoMetallic (SMOM) method...

Бүрэн тодорхойлолт

Номзүйн дэлгэрэнгүй
Үндсэн зохиолч:	Bukvic, AJ
Бусад зохиолчид:	Weller, AS
Формат:	Дипломын ажил
Хэвлэсэн:	2020
Нөхцлүүд:	Chemistry

Ижил төстэй зүйлс

Modulation of σ-alkane interactions in [Rh(L2)(alkane)]+ Solid-State Molecular Organometallic (SMOM) systems by variation of the chelating phosphine and alkane: Access to η2,η2-σ-alkane Rh(I), η1-σ-alkane Rh(III) complexes, and alkane encapsulation
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Room temperature acceptorless alkane dehydrogenation from molecular σ-alkane complexes
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Synthesis and Characterization of a Rhodium(I) σ-Alkane Complex in the Solid State
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Synthesis and characterization of a rhodium(I) σ-alkane complex in the solid state.
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Synthesis and characterization of a rhodium(I) σ-alkane complex in the solid state.
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Pressure Driven Alkane Dehydrogenation by Palladium Metal
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Dehydrogenation of alkanes to alkenes using CO2 as mild oxidant; an attractive method of CO2 utilisation
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Reversible encapsulation of xenon and CH2Cl2 in a solid-state molecular organometallic framework (Guest@SMOM)
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The synthesis of cobalt(I) σ-alkane complex and pincer complex catalysts for the generation of polyaminoborane on scale
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Catalysis for CO2 activation reactions with light alkanes
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Kinetic Insights into Boron-Based Materials Catalyzed Oxidative Dehydrogenation of Light Alkanes
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