Solid-State Organometallic Chemistry (SMOM): synthesis, alkane dehydrogenation and surface modification of crystalline σ-alkane complexes

Solid-State Organometallic Chemistry (SMOM): synthesis, alkane dehydrogenation and surface modification of crystalline σ-alkane complexes

This thesis reports the synthesis of single-crystalline σ-alkane complexes of rhodium. These are synthesised by the hydrogenation of precursor alkene or diene complexes in solid/gas single-crystal to single-crystal (SC-SC) transformations, using the Solid-State Molecular OrganoMetallic (SMOM) method...

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Manylion Llyfryddiaeth
Prif Awdur:	Bukvic, AJ
Awduron Eraill:	Weller, AS
Fformat:	Traethawd Ymchwil
Cyhoeddwyd:	2020
Pynciau:	Chemistry

Eitemau Tebyg

Modulation of σ-alkane interactions in [Rh(L2)(alkane)]+ Solid-State Molecular Organometallic (SMOM) systems by variation of the chelating phosphine and alkane: Access to η2,η2-σ-alkane Rh(I), η1-σ-alkane Rh(III) complexes, and alkane encapsulation
gan: Martinez-Martinez, AJ, et al.
Cyhoeddwyd: (2018)

Room temperature acceptorless alkane dehydrogenation from molecular σ-alkane complexes
gan: McKay, AI, et al.
Cyhoeddwyd: (2019)

Synthesis and Characterization of a Rhodium(I) σ-Alkane Complex in the Solid State
gan: Pike, S, et al.
Cyhoeddwyd: (2012)

Synthesis and characterization of a rhodium(I) σ-alkane complex in the solid state.
gan: Pike, S, et al.
Cyhoeddwyd: (2012)

Synthesis and characterization of a rhodium(I) σ-alkane complex in the solid state.
gan: Pike, S, et al.
Cyhoeddwyd: (2012)

Pressure Driven Alkane Dehydrogenation by Palladium Metal
gan: Mungo Frost, et al.
Cyhoeddwyd: (2023-03-01)

Dehydrogenation of alkanes to alkenes using CO2 as mild oxidant; an attractive method of CO2 utilisation
gan: Gao, Y
Cyhoeddwyd: (2023)

Reversible encapsulation of xenon and CH2Cl2 in a solid-state molecular organometallic framework (Guest@SMOM)
gan: Martínez‐Martínez, AJ, et al.
Cyhoeddwyd: (2019)

The synthesis of cobalt(I) σ-alkane complex and pincer complex catalysts for the generation of polyaminoborane on scale
gan: Boyd, TM
Cyhoeddwyd: (2021)

Catalysis for CO2 activation reactions with light alkanes
gan: Du, X
Cyhoeddwyd: (2016)

Synthesis and Modification of Catalysts for the Partial Oxidation of n-Alkanes
gan: N. Golub, et al.
Cyhoeddwyd: (1999-05-01)

Interfacial tension of the water/n-alkane interface
gan: Goebel, A, et al.

Dehydrogenative Coupling of Alkanes and Benzene Enhanced by Slurry-Phase Interparticle Hydrogen Transfer
gan: Moe Takabatake, et al.
Cyhoeddwyd: (2021-01-01)

Kinetic Insights into Boron-Based Materials Catalyzed Oxidative Dehydrogenation of Light Alkanes
gan: Hao Tian, et al.
Cyhoeddwyd: (2024-04-01)

Controlling structure and reactivity in cationic Solid–State Molecular OrganoMetallic (SMOM) systems using anion templating
gan: McKay, A, et al.
Cyhoeddwyd: (2018)

Organometallic chemistry /
gan: Fairlamb, Ian J. S., editor, et al.
Cyhoeddwyd: (2012)

Organometallic chemistry
gan: Fairlamb, Ian J. S., editor of compilation, et al.
Cyhoeddwyd: (2014)

Organometallic chemistry /
Cyhoeddwyd: (2008)

Organocatalytic C-H functionalization of simple alkanes
gan: Su, Fen, et al.
Cyhoeddwyd: (2023)

Oxygen-containing heterocycles from σ, σ, ω, ω-alkane-tetracarboxylates and electro-generated formaldehyde
gan: Michail N. Elinson, et al.
Cyhoeddwyd: (2001-12-01)

Methods for the oxidation of organic compounds : alkanes, alkenes, alkynes and arenes
gan: 426775 Haines, Alan H.
Cyhoeddwyd: (1985)

Theoretical Prediction of the Efficiency of Hydrogen Production via Alkane Dehydrogenation in Catalytic Membrane Reactor
gan: Ekaterina V. Shelepova, et al.
Cyhoeddwyd: (2021-09-01)

Organometallic chemistry and catalysis /
gan: 399972 Astruc, Didier
Cyhoeddwyd: (2007)

Distribution Of N-Alkanes In Surface Soils Of Kuantan City, Pahang, Malaysia
gan: Tay, Joo Hui, et al.
Cyhoeddwyd: (2013)

Organometallic chemistry
gan: Open University. The Nature of Chemistry Course Team
Cyhoeddwyd: (1977)

Principles of organometallic chemistry/
gan: 241801 Powell, P.
Cyhoeddwyd: (1988)

Advances in organometallic chemistry.
gan: Hill, Anthony F., editor, et al.
Cyhoeddwyd: (2011)

Advances in organometallic chemistry.
gan: Hill, Anthony F., editor, et al.
Cyhoeddwyd: (2012)

Organometallic chemistry : an overview /
gan: 410509 Thayer, John S.
Cyhoeddwyd: (1988)

Computational organometallic chemistry /
gan: Cundari, Thomas R
Cyhoeddwyd: (2001)

Complex formation and liquid-liquid extraction of silver with cyclic and open-chain oxathia alkanes /
gan: Dietze, Frank

Alkan’s for organ
gan: Michael W. Beauvois
Cyhoeddwyd: (2018-01-01)

Experimental organometallic chemistry : a practicum in synthesis and characterization/
gan: Wayda, Andrea L., et al.
Cyhoeddwyd: (1987)

Tuning the Selectivity in the Nonoxidative Alkane Dehydrogenation Reaction by Potassium-Promoted Zeolite-Encapsulated Pt Catalysts
gan: Nengfeng Gong, et al.
Cyhoeddwyd: (2024-12-01)

Organometallic chemistry reviews/
Cyhoeddwyd: (1976)

Principles of organometallic chemistry /
gan: Coates, G. E. (Geoffrey Edward), 1917-
Cyhoeddwyd: (1977)

The surface scientist's guide to organometallic chemistry/
gan: 195349 Albert, Mark R., et al.
Cyhoeddwyd: (1987)

Structural Insights into Diversity and n-Alkane Biodegradation Mechanisms of Alkane Hydroxylases
gan: Yurui eJi, et al.
Cyhoeddwyd: (2013-03-01)

Organometallic chemistry research perspectives /
gan: Irwin, Richard P.
Cyhoeddwyd: (2007)

Inverse isotope effects in single-crystal to single-crystal reactivity and the isolation of a rhodium cyclooctane σ-alkane complex
gan: Doyle, LR, et al.
Cyhoeddwyd: (2022)