How Much Supporting Electrolyte Is Required to Make a Cyclic Voltammetry Experiment Quantitatively "Diffusional"? A Theoretical and Experimental Investigation

Theory is presented for cyclic voltammetry at a hemispherical electrode under conditions where the electric field is nonzero and migration is significant to mass transport. The nonlinear set of differential equations formed by combining the Nernst-Planck equation and the Poisson equation are solved...

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Bibliographic Details
Main Authors: Dickinson, E, Limon-Petersen, J, Rees, N, Compton, R
Format: Journal article
Language:English
Published: 2009