Enhanced chemical reversibility of redox processes in cyanine dye rotaxanes

When a cyanine dye is encapsulated inside the cavity of α-cyclodextrin, by rotaxane formation, its one-electron oxidation and reduction become reversible, due to a thousand-fold increase in the kinetic chemical stability of the oxidised and reduced forms of the chromophore.

Bibliographic Details
Main Authors: Buston, J, Marken, F, Anderson, H
Format: Journal article
Language:English
Published: 2001