Recent developments in the chemistry of lithiated epoxides

Recent developments in the chemistry of lithiated epoxides

Although the lithium base-induced β-elimination of epoxides to allylic alcohols is a well-known reaction, α-lithiation has also been described many times. The resulting lithiated epoxides, first postulated as intermediates by Cope in 1951, have been invoked in a wide range of reactions, with their c...

Bibliografski detalji
Glavni autori:	Hodgson, D, Gras, E
Format:	Journal article
Jezik:	English
Izdano:	2002

Slični predmeti

Substituted epoxides by lithiation of terminal epoxides.
od: Hodgson, D, i dr.
Izdano: (2004)

Expanding the utility of lithiated epoxides and aziridines in synthesis
od: Hodgson, D, i dr.
Izdano: (2006)

Stereocontrolled syntheses of (-)-cubebol and (-)-10-epicubebol involving intramolecular cyclopropanation of alpha-lithiated epoxides.
od: Hodgson, D, i dr.
Izdano: (2010)

Alkenes from β-lithiooxyphosphonium ylides generated by trapping α-lithiated terminal epoxides with triphenylphosphine.
od: Hodgson, D, i dr.
Izdano: (2012)

Alkenes from β-lithiooxyphosphonium ylides generated by trapping α-lithiated terminal epoxides with triphenylphosphine
od: David. M. Hodgson, i dr.
Izdano: (2012-11-01)

Chiral epoxides by desymmetrizing deprotonation of meso-epoxides.
od: Hodgson, D, i dr.
Izdano: (2002)

syn-β-Hydroxyallylic silanes from terminal epoxide α-lithiation-silylation and alkenylation: application to the tetrahydrofuran portion of the lytophilippines.
od: Hodgson, D, i dr.
Izdano: (2012)

Lithiated azetidine and azetine chemistry
od: Pearson, CI
Izdano: (2014)

Dimerization of lithiated terminal aziridines.
od: Hodgson, D, i dr.
Izdano: (2006)

LITHIATION-STANNYLATION CHEMISTRY FOR NUCLEOSIDE SYNTHESIS
od: Tanaka, Hiromichi, i dr.
Izdano: (2001-09-01)

Enantioselective synthesis of epoxides by alpha-deprotonation--electrophile trapping of achiral epoxides.
od: Hodgson, D, i dr.
Izdano: (2003)

Lithiation-electrophilic substitution of N-thiopivaloylazetidine.
od: Hodgson, D, i dr.
Izdano: (2010)

Lithiation: Electrophile trapping of simple aziridine building blocks
od: Hughes, S, i dr.
Izdano: (2007)

Substituted aziridines by lithiation-electrophile trapping of terminal aziridines.
od: Hodgson, D, i dr.
Izdano: (2005)

Dimerization and isomerization reactions of alpha-lithiated terminal aziridines.
od: Hodgson, D, i dr.
Izdano: (2007)

Lithiation-induced migrations from nitrogen to carbon in terminal aziridines.
od: Hodgson, D, i dr.
Izdano: (2007)

Thieme Chemistry Journal Awardees - Where Are They Now? Synthesis of (-)-Cubebol by Intramolecular Cyclopropanation of a Terminal Epoxide
od: Hodgson, D, i dr.
Izdano: (2009)

Enantioselective alpha-deprotonation of epoxides.
od: Hodgson, D
Izdano: (2001)

Metalated Epoxides and Aziridines in Synthesis
od: Hodgson, D, i dr.
Izdano: (2006)

Functionalized alkenes from epoxides
od: Hodgson, D, i dr.
Izdano: (2004)

First direct deprotonation-electrophile trapping of simple epoxides: synthesis of alpha,beta-epoxysilanes from terminal epoxides.
od: Hodgson, D, i dr.
Izdano: (2001)

Epoxydisilanes by direct double silylation of terminal epoxides
od: Hodgson, D, i dr.
Izdano: (2004)

Amine Protection/α-Activation with the tert-Butoxythiocarbonyl Group: Application to Azetidine Lithiation-Electrophilic Substitution.
od: Hodgson, D, i dr.
Izdano: (2015)

Enantioselective desymmetrisation of achiral epoxides
od: Hodgson, D, i dr.
Izdano: (1996)

Unraveling the surface chemistry processes in lithiated and boronized plasma material interfaces under extreme conditions
od: P.S. Krstic, i dr.
Izdano: (2018-07-01)

Widening the usefulness of epoxides and aziridines in synthesis
od: Hodgson, D, i dr.
Izdano: (2007)

Intramolecular cyclopropanation of unsaturated terminal epoxides.
od: Hodgson, D, i dr.
Izdano: (2004)

Widening the usefulness of epoxides and aziridines in synthesis
od: Hodgson, D, i dr.
Izdano: (2007)

α-Lithiation-electrophile trapping of N-thiopivaloylazetidin-3-ol: stereoselective synthesis of 2-substituted 3-hydroxyazetidines.
od: Hodgson, D, i dr.
Izdano: (2013)

Enantioselective alpha-deprotonation-rearrangement of meso-epoxides
od: Hodgson, D, i dr.
Izdano: (1996)

Deprotonation-electrophile trapping of terminal epoxides.
od: Hodgson, D, i dr.
Izdano: (2005)

β-Lithiation of oxazolinyloxiranes: synthetic utility
od: Vito Capriati, i dr.
Izdano: (2003-09-01)

Isoprene-promoted lithiation of 1-phenylimidazole
od: Rosario Torregrosa, i dr.
Izdano: (2007-04-01)

Lithiation and electrophilic substitution of dimethyl triazones
od: Han, Sunkyu, i dr.
Izdano: (2015)

Light-assist electrochemical lithiation to silicon semiconductor
od: Nur Chamidah, i dr.
Izdano: (2023-04-01)

Selective lithiation of 1-chloro-n-phenylsulfanylalkanes
od: Abdeslam Abou, i dr.
Izdano: (2006-11-01)

An enantioselective epoxide rearrangement - Claisen rearrangement approach to prostaglandins and (+)-iridomyrmecin
od: Hodgson, D, i dr.
Izdano: (1997)

Enamines from terminal epoxides and hindered lithium amides.
od: Hodgson, D, i dr.
Izdano: (2004)

First-principles study of iron oxyfluorides and lithiation of FeOF
od: Chevrier, Vincent L., i dr.
Izdano: (2013)

Ligand effects in the organolithium-mediated enantioselective alpha-deprotonation of achiral epoxides
od: Hodgson, D, i dr.
Izdano: (1997)