Two methods for amplifying the optical nonlinearity of a conjugated porphyrin polymer: transmetallation and self-assembly
A new soluble conjugated metalloporphyrin polymer has been synthesised as its complex with zinc(II), lead(II) and copper(II) and as the free-base. The zinc complex aggregates in non-coordinating solvents, due to coordination of the amide side-chains to the zinc centres. These aggregates dissociate o...
| Main Authors: | , , , , |
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| Formato: | Conference item |
| Publicado em: |
2003
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