Coordination and activation of the BF molecule.

No CO: Fluoroborylene (BF), isoelectronic with CO and N(2), can be trapped by a transition metal. The structurally characterized complex [{CpRu(CO)(2)}(2)(mu-BF)] contains an unsupported bridging BF ligand, which is unprecedented in the structural chemistry of CO. With AlCl(3) , metal-bound CO coord...

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Bibliographic Details
Main Authors: Vidovic, D, Aldridge, S
Format: Journal article
Language:English
Published: 2009