Phosphazene catalyzed addition to electron-deficient alkynes: the importance of non-linear allenyl intermediates upon stereoselectivity.
An ONIOM QM/MM study on the mechanism of the Michael addition to triple bonds catalyzed by chiral diiminophosphorane catalysts has been performed to understand the stereoselectivity of the product olefin. Our results are consistent with the experimental enantioselectivity, but more importantly, reve...
| প্রধান লেখক: | , |
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| বিন্যাস: | Journal article |
| ভাষা: | English |
| প্রকাশিত: |
American Chemical Society
2017
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