Intercepting a transient phosphino‐arsinidene

A phosphino‐arsinidene derived from a diazaphospholidine scaffold (Ar**NCH2)2PAs (where Ar**=2,6‐bis[(4‐tert‐butylphenyl)methyl]‐4‐methylphenyl) was generated in situ and trapped with a range of reagents. Metathesis reactions between (Ar**NCH2)2PCl and either [Na(18‐crown‐6)][AsCO] or [Na(dioxane)x]...

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Bibliographic Details
Main Authors: Hinz, A, Hansmann, M, Bertrand, G, Goicoechea, J
Format: Journal article
Language:English
Published: Wiley‐VCH Verlag 2018