Electrophilic fluorodesilylation of allenylmethylsilanes: a novel entry to 2-fluoro-1,3-dienes.

[reaction: see text] Various fluorodienes were prepared by treatment of the corresponding allenylmethylsilanes with Selectfluor. This is the first route to these compounds not based on the use of a fluorinated building block. The reaction allows the preparation of 2-fluoro-1,3-dienes with several su...

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Bibliographic Details
Main Authors: Pacheco, M, Gouverneur, V
Format: Journal article
Language:English
Published: 2005