Electrophilic fluorodesilylation of allenylmethylsilanes: a novel entry to 2-fluoro-1,3-dienes.
[reaction: see text] Various fluorodienes were prepared by treatment of the corresponding allenylmethylsilanes with Selectfluor. This is the first route to these compounds not based on the use of a fluorinated building block. The reaction allows the preparation of 2-fluoro-1,3-dienes with several su...
| Автори: | , |
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| Формат: | Journal article |
| Мова: | English |
| Опубліковано: |
2005
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| _version_ | 1826280282232193024 |
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| author | Pacheco, M Gouverneur, V |
| author_facet | Pacheco, M Gouverneur, V |
| author_sort | Pacheco, M |
| collection | OXFORD |
| description | [reaction: see text] Various fluorodienes were prepared by treatment of the corresponding allenylmethylsilanes with Selectfluor. This is the first route to these compounds not based on the use of a fluorinated building block. The reaction allows the preparation of 2-fluoro-1,3-dienes with several substitution patterns, including di- and trisubstituted compounds. |
| first_indexed | 2024-03-07T00:11:21Z |
| format | Journal article |
| id | oxford-uuid:79594b0d-c686-4145-9447-84dd144fda27 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T00:11:21Z |
| publishDate | 2005 |
| record_format | dspace |
| spelling | oxford-uuid:79594b0d-c686-4145-9447-84dd144fda272022-03-26T20:36:48ZElectrophilic fluorodesilylation of allenylmethylsilanes: a novel entry to 2-fluoro-1,3-dienes.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:79594b0d-c686-4145-9447-84dd144fda27EnglishSymplectic Elements at Oxford2005Pacheco, MGouverneur, V[reaction: see text] Various fluorodienes were prepared by treatment of the corresponding allenylmethylsilanes with Selectfluor. This is the first route to these compounds not based on the use of a fluorinated building block. The reaction allows the preparation of 2-fluoro-1,3-dienes with several substitution patterns, including di- and trisubstituted compounds. |
| spellingShingle | Pacheco, M Gouverneur, V Electrophilic fluorodesilylation of allenylmethylsilanes: a novel entry to 2-fluoro-1,3-dienes. |
| title | Electrophilic fluorodesilylation of allenylmethylsilanes: a novel entry to 2-fluoro-1,3-dienes. |
| title_full | Electrophilic fluorodesilylation of allenylmethylsilanes: a novel entry to 2-fluoro-1,3-dienes. |
| title_fullStr | Electrophilic fluorodesilylation of allenylmethylsilanes: a novel entry to 2-fluoro-1,3-dienes. |
| title_full_unstemmed | Electrophilic fluorodesilylation of allenylmethylsilanes: a novel entry to 2-fluoro-1,3-dienes. |
| title_short | Electrophilic fluorodesilylation of allenylmethylsilanes: a novel entry to 2-fluoro-1,3-dienes. |
| title_sort | electrophilic fluorodesilylation of allenylmethylsilanes a novel entry to 2 fluoro 1 3 dienes |
| work_keys_str_mv | AT pachecom electrophilicfluorodesilylationofallenylmethylsilanesanovelentryto2fluoro13dienes AT gouverneurv electrophilicfluorodesilylationofallenylmethylsilanesanovelentryto2fluoro13dienes |