A stable two-coordinate acyclic silylene.

Simple two-coordinate acyclic silylenes, SiR(2), have hitherto been identified only as transient intermediates or thermally labile species. By making use of the strong σ-donor properties and high steric loading of the B(NDippCH)(2) substituent (Dipp = 2,6-(i)Pr(2)C(6)H(3)), an isolable monomeric spe...

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Váldodahkkit: Protchenko, A, Birjkumar, K, Dange, D, Schwarz, A, Vidovic, D, Jones, C, Kaltsoyannis, N, Mountford, P, Aldridge, S
Materiálatiipa: Journal article
Giella:English
Almmustuhtton: 2012