New ligand platforms for developing the chemistry of the Ti=N-NR2 functional group and the insertion of alkynes into the N-N bond of a Ti=N-NPh2 ligand.

Míreanna comhchosúla

• Titanium alkoxyimido (Ti=N-OR) complexes: reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands.
  de réir: Schwarz, A, et al.
  Foilsithe / Cruthaithe: (2011)
• Reaction site diversity in the reactions of titanium hydrazides with organic nitriles, isonitriles and isocyanates: Ti=N(α) cycloaddition, Ti=N(α) insertion and N(α) -N(β) bond cleavage.
  de réir: Schofield, A, et al.
  Foilsithe / Cruthaithe: (2011)
• Reaction Site Diversity in the Reactions of Titanium Hydrazides with Organic Nitriles, Isonitriles and Isocyanates: Ti==N(α) Cycloaddition, Ti==N(α) Insertion and N(α)--N(β) Bond Cleavage.
  de réir: Schofield, A, et al.
  Foilsithe / Cruthaithe: (2010)
• M=N(alpha) cycloaddition and N(alpha)-N(beta) insertion in the reactions of titanium hydrazido compounds with alkynes: a combined experimental and computational study.
  de réir: Schofield, A, et al.
  Foilsithe / Cruthaithe: (2010)
• Synthesis and reactivity of the imidotungsten methyl cation [W(N2Npy)(NPh)Me]+: CO2 adds to the W=NPh bond and does not insert into the W-Me bond.
  de réir: Ward, B, et al.
  Foilsithe / Cruthaithe: (2002)