New ligand platforms for developing the chemistry of the Ti=N-NR2 functional group and the insertion of alkynes into the N-N bond of a Ti=N-NPh2 ligand.
Two broadly applicable strategies for extending the available ligand platforms of the virtually unexplored terminal Ti=N-NR2 functional group are described, along with the highly selective room temperature insertion of alkynes into the N-N bond of Ti{MeN(CH2CH2NSiMe3)2}(NNPh2)(py) and the catalytic...
| Hlavní autoři: | , , , , , |
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| Médium: | Journal article |
| Jazyk: | English |
| Vydáno: |
2007
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