Asymmetric catalysis with 7-ring chelate diphosphines: DIOP, BINAP and conformational mobility

The conformations of two classes of 7-ring diphosphine metal chelate have been analysed, based on DIOP- or BINAP-type structures. A combination of X-ray analysis, DFT calculations, data analysis based on the CDS structure database and solution NMR studies has been employed. The conformational flexib...

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Bibliographic Details
Main Authors: Raskatov, J, Thompson, A, Brown, J
Format: Journal article
Language:English
Published: 2010