The relative stabilities of cyclic dicationic derivatives of diphosphanes with three (3P) or four (4P) linked phosphorus atoms.

Reaction of a diphosphane with a chlorophosphane in the presence of SnCl(2) or AlCl(3) leads to the formation of dicationic heterocycles with three (3P) or four (4P) linked phosphorus atoms. Some 3P derivatives with small alkyl substituents may also be prepared by direct alkylation of cyclic triphos...

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Bibliographic Details
Main Authors: Bashforth, R, Boyall, A, Coffer, P, Dillon, K, Goeta, A, Howard, J, Kenwright, A, Probert, MR, Shepherd, H, Thompson, A
Format: Journal article
Language:English
Published: 2012