Biomimetic rearrangements of simplified labdane diterpenoids

Simplified ethyl-substituted labdane diterpenoids 14 and 19 have been synthesised from (+)-sclareolide (18). Biomimetic rearrangements of these compounds, involving stereospecific 1,2-alkyl and hydride shifts, have been carried out by treatment with a variety of Lewis and protic acids. Halimane comp...

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Main Authors: George, J, McArdle, M, Baldwin, J, Adlington, R
格式: Conference item
出版: 2010