New chemical insights using weakly supported voltammetry: Ion pairing in the EC 2 reduction of 2,6-diphenylpyrylium in acetonitrile
Pairing effect: Varying the concentration of support electrolyte in the electrochemical EC 2 reduction of 2,6-diphenylpyrylium reveals the presence of ion pairing between the electroactive species and BF 4-. Experiment and theory are shown to be in good agreement only if ion pairing is included in t...
Main Authors: | Barnes, E, Wang, Y, Belding, SR, Compton, R |
---|---|
Format: | Journal article |
Sprog: | English |
Udgivet: |
2012
|
Lignende værker
-
New chemical insights using weakly supported voltammetry: ion pairing in the EC2 reduction of 2,6-diphenylpyrylium in acetonitrile.
af: Barnes, E, et al.
Udgivet: (2012) -
Chemical instability promotes apparent electrochemical irreversibility: Studies on the electrode kinetics of the one electron reduction of the 2,6-diphenylpyrylium cation in acetonitrile solution
af: Streeter, I, et al.
Udgivet: (2007) -
Cyclic voltammetry in weakly supported media The reduction of the cobaltocenium cation in acetonitrile - Comparison between theory and experiment
af: Limon-Petersen, J, et al.
Udgivet: (2010) -
Voltammetry in the absence of excess supporting electrolyte - ECE-DISP1 reactions: The electrochemical reduction of 2-nitrobromobenzene in acetonitrile solvent
af: Barnes, E, et al.
Udgivet: (2011) -
Cyclic voltammetry in the absence of excess supporting electrolyte offers extra kinetic and mechanistic insights: comproportionation of anthraquinone and the anthraquinone dianion in acetonitrile.
af: Belding, SR, et al.
Udgivet: (2010)