Intermediates in the intermolecular, asymmetric Heck arylation of dihydrofurans

Double isomerization results in a Pd alkyl compound with unexpected structure, which is stable until -40, from the reaction of the Pd complex shown on the right with 2,3-dihydrofuran. The course of the asymmetric Heck reaction was followed by NMR spectroscopy. P(a)P(b) = (S)-BINAP.

Bibliographic Details
Main Authors: Hii, K, Claridge, T, Brown, J
Format: Journal article
Language:English
Published: 1997