Intermediates in the intermolecular, asymmetric Heck arylation of dihydrofurans
Double isomerization results in a Pd alkyl compound with unexpected structure, which is stable until -40, from the reaction of the Pd complex shown on the right with 2,3-dihydrofuran. The course of the asymmetric Heck reaction was followed by NMR spectroscopy. P(a)P(b) = (S)-BINAP.
Main Authors: | , , |
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Format: | Journal article |
Language: | English |
Published: |
1997
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