Intermediates in the intermolecular, asymmetric Heck arylation of dihydrofurans

Double isomerization results in a Pd alkyl compound with unexpected structure, which is stable until -40, from the reaction of the Pd complex shown on the right with 2,3-dihydrofuran. The course of the asymmetric Heck reaction was followed by NMR spectroscopy. P(a)P(b) = (S)-BINAP.

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Hlavní autoři: Hii, K, Claridge, T, Brown, J
Médium: Journal article
Jazyk:English
Vydáno: 1997