Studies towards the stereoselective synthesis of alkenes

Studies towards the stereoselective synthesis of alkenes

<p>The work presented in this thesis mainly describes the development of new reactions of β-lithiooxyphosphonium ylides to access stereodefined substituted alkenes in a highly convergent fashion.</p> <p>Firstly, β-lithiooxy ylides prepared from aldehydes and phosphonium ylides were...

Cur síos iomlán

Sonraí bibleagrafaíochta
Príomhchruthaitheoir:	Arif, T
Rannpháirtithe:	Hodgson, DM
Formáid:	Tráchtas
Teanga:	English
Foilsithe / Cruthaithe:	2011
Ábhair:	Organic synthesis Organometallic Chemistry Chemistry & allied sciences Organic chemistry Synthetic organic chemistry

Míreanna comhchosúla

Transition metal catalysed C-C bond formation via C-H functionalisation
de réir: Truscott, FR
Foilsithe / Cruthaithe: (2012)

Aziridinations of tethered allenes
de réir: Feast, GC
Foilsithe / Cruthaithe: (2011)

Phosphoramidite ligand design for the enantioselective conjugate addition of alkylzirconium reagents to enones
de réir: Roth, PMC
Foilsithe / Cruthaithe: (2014)

Tandem catalytic processes involving Rhodium-catalysed intermolecular hydroacylation
de réir: Lenden, P
Foilsithe / Cruthaithe: (2011)

Reactions of allenylpalladium intermediates in organic synthesis
de réir: Daniels, DSB
Foilsithe / Cruthaithe: (2013)

Enantioselective synthesis and reactivity of benzylic fluorides
de réir: Blessley, G, et al.
Foilsithe / Cruthaithe: (2013)

Studies towards the total synthesis of manzamine A
de réir: Hawkins, A
Foilsithe / Cruthaithe: (2013)

Palladacycle-catalyzed asymmetric hydrophosphination of achiral heterobicyclic alkenes
de réir: Ong, Yew Jin
Foilsithe / Cruthaithe: (2018)

Palladium mediated allylic fluorination
de réir: Hollingworth, C
Foilsithe / Cruthaithe: (2013)

Rhodium catalysed hydroacylation reactions in the synthesis of heterocycles
de réir: Ylioja, P
Foilsithe / Cruthaithe: (2011)

Lithiated azetidine and azetine chemistry
de réir: Pearson, CI
Foilsithe / Cruthaithe: (2014)

Alkaloids from transannular iodoaminations
de réir: Brock, E
Foilsithe / Cruthaithe: (2012)

Stereoselective cyclopropanations of allylic amines and derivatives
de réir: Ling, K, et al.
Foilsithe / Cruthaithe: (2009)

Palladium-catalysed cascade cyclisation of alkynyl silanes and studies towards rubriflordilactone A
de réir: Cordonnier, M, et al.
Foilsithe / Cruthaithe: (2011)

The synthesis and biology of iminosugars and their precursors
de réir: Ayers, B, et al.
Foilsithe / Cruthaithe: (2014)

Catalytic asymmetric carbon-carbon bond formation using alkenes as alkylmetal equivalents
de réir: Maksymowicz, R
Foilsithe / Cruthaithe: (2014)

Asymmetric synthesis of piperidine alkaloids
de réir: Thomson, A, et al.
Foilsithe / Cruthaithe: (2012)

Development of catalytic methods to exploit sulfur dioxide in organic synthesis
de réir: Emmett, EJ
Foilsithe / Cruthaithe: (2014)

Transition metal catalysis in the presence of fluorinating reagents
de réir: Hopkinson, M
Foilsithe / Cruthaithe: (2011)

New methods for the construction of C-18F bonds
de réir: Stenhagen, I
Foilsithe / Cruthaithe: (2014)

Stereoselective β-C-glycosylation by a palladium-catalyzed decarboxylative allylation : formal synthesis of aspergillide A
de réir: Xiang, Shaohua, et al.
Foilsithe / Cruthaithe: (2014)

Determining the structures of halogenated marine natural products by total synthesis
de réir: Dyson, BS
Foilsithe / Cruthaithe: (2011)

Towards the stereoselective synthesis of bicyclic and tricyclic alkaloid natural products
de réir: Patcharaporn Sae-Lao
Foilsithe / Cruthaithe: (2012)

Synthesis of heterocycles via palladium-catalysed direct arylation
de réir: Yagoubi, M
Foilsithe / Cruthaithe: (2011)

Application of hydroformylation for the stereoselective synthesis of piperidine alkaloids
de réir: Sivarajan Kasinathan
Foilsithe / Cruthaithe: (2014)

Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes
de réir: Lim, Maricar Bungabong
Foilsithe / Cruthaithe: (2009)

Asymmetric synthesis of functionalized chiral diphosphines via organopalladium promoted hydrophosphination and diels-alder reactions
de réir: Yuan, Mingjun
Foilsithe / Cruthaithe: (2011)

Total synthesis of (–)-nakadomarin A and an approach to the diazatricyclic core of the madangamines
de réir: Kyle, A
Foilsithe / Cruthaithe: (2012)

Exploring and exploiting selectivity in Rhodium-catalysed hydroacylation reactions
de réir: Poingdestre, SJ
Foilsithe / Cruthaithe: (2012)

Synthesis studies towards daphlongeranine B
de réir: Kallstrom, JED
Foilsithe / Cruthaithe: (2013)

Palladium-catalysed cyclisations of bromoenynamides in the synthesis and applications of amidodienes
de réir: Greenaway, R
Foilsithe / Cruthaithe: (2013)

Palladium- and copper-catalysed heterocycle synthesis
de réir: Ball, C
Foilsithe / Cruthaithe: (2014)

The synthesis and reactivity of cationic terminal borylene complexes
de réir: Pierce, G, et al.
Foilsithe / Cruthaithe: (2010)

Asymmetric conjugate additions of alkylzirconocenes to cyclopent-4-ene-1,3-dione monoacetals.
de réir: Rideau, E, et al.
Foilsithe / Cruthaithe: (2015)

Synthesis and elaboration of heterocycles via palladium-catalyzed C-H functionalization
de réir: Gerelle, M
Foilsithe / Cruthaithe: (2012)

Reaction engineering for protein modification: tools for chemistry and biology
de réir: Chalker, J
Foilsithe / Cruthaithe: (2011)

Novel palladium-catalysed routes to aromatic heterocycles
de réir: Pilgrim, B, et al.
Foilsithe / Cruthaithe: (2013)

Solution reactivity studies of group 15 Zintl anions towards unsaturated substrates
de réir: Turbervill, R
Foilsithe / Cruthaithe: (2014)

Development of new carbon-carbon bond forming reactions through 1,4-migration of rhodium
de réir: Ming, Jialin
Foilsithe / Cruthaithe: (2018)

Palladium-catalysed heterocycle synthesis
de réir: Sadig, JER
Foilsithe / Cruthaithe: (2012)