Total synthesis of antascomicin B.
(Chemical Equation Presented) The structurally enticing antascomicin B (1), which exhibits potent immunosuppressant-antagonizing properties, has a complex polyketide structure. Key steps in its enantioselective total synthesis include a transannular catechol-templated Dieckmann reaction to assemble...
Váldodahkkit: | , , , , , , , , |
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Materiálatiipa: | Journal article |
Giella: | English |
Almmustuhtton: |
2005
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